Synthesis of Functionalized Hydrazines: Facile Homogeneous (N‐Heterocyclic Carbene)‐Palladium(0)‐Catalyzed Diboration and Silaboration of Azobenzenes
نویسندگان
چکیده
The bis(N-heterocyclic carbene)(diphenylacetylene)palladium complex [Pd(ITMe)2(PhC≡CPh)] (ITMe=1,3,4,5-tetramethylimidazol-2-ylidene) acts as a highly active pre-catalyst in the diboration and silaboration of azobenzenes to synthesize a series of novel functionalized hydrazines. The reactions proceed using commercially available diboranes and silaboranes under mild reaction conditions.
منابع مشابه
An experimental and theoretical study into the facile, homogenous (N-heterocyclic carbene)2-Pd(0) catalyzed diboration of internal and terminal alkynes
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